Evaluasi Kemampuan HCl dan H2SO4 Sebagai Aktivator Adsorben Bubuk Kulit Batang Sagu (Metroxylon Sagu)

  • Mukhlis . University of Riau
  • Itnawita . University Of Riau
  • Ayu Chandra Kartika University Of Riau
  • Fika Filia Cani University Of Riau
Keywords: Aktivator, Kulit Batang Sagu, Adsorben

Abstract

Sago stem bark powder (Metroxylon sago) has the potential as an adsorbent because it contains cellulose, hemicellulose, and lignin. This study`s purpose was to determine the ability of the chemical activator in the hydrochloric acid and sulfuric acid to improve the adsorbent quality of sago stem bark powder according to SNI 06-3730-1995 standards. The method used is the bath system, where the sago stem bark powder is activated by soaking with HCl and H2SO4 for 24 hours using a variation of the adsorbent ratio and activator weight 1: 1, 1: 2, and 1: 3. The analysis was tested through characterization including moisture content, ash content, iodine absorption, and methylene blue absorption, as well as functional groups. From the research results, it was found that the two activators showed an optimal ratio of 1: 2 to provide optimal conditions for moisture content, ash content, iodine and methylene blue adsorption, surface area each of 1.64%; 3.14%; 261.41 mg/g; 4.80 mg/g; 17.76 m2/g for HCl activator and 2.67%; 3.20%; 261.10 mg/g; 4.79 mg/g; 17.67 m2/g for H2SO4 activator. From it this study can be concluded that the use of HCl and H2SO4 solutions did not show a significant difference as an activator to improve the quality of the sago stem bark powder adsorbent, the absorption value of iodine and methylene blue both activators have not been able to make sago stem bark powder as an adsorbent according to SNI 06-3730-1995 standards.

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References

Adegboyega, S. O., Olusegun, A. A., Michael, S. O., Mku, T. I., & Sam, S. A. (2015). Preparation of phosphoric acid activated carbons from Canarium Schweinfurthii Nutshell and its role in methylene blue adsorption. Journal of Chemical Engineering and Materials Science, 6(2), 9–14.

Ahmadpour, A., & Do, D. D. (1997). The preparation of activated carbon from macadamia nutshell by chemical activation. Carbon, 35(12), 1723–1732.

Amri, T. A., Priyanto, A., Ramadhan, F., & Gustantia, Y. P. (2017). Buah Pinang Sebagai Adsorben. Potensi Limbah Tongkol Jagung Dan Sabut Pinang Sebagai Adsorben, 2, 23–30.

Atkins, P. W. (1990). Kimia Fisika. Erlangga.

Aulia, R., Juliasih, N. L. G. R., & Rinawati, R. (2018). Pembuatan dan karakterisasi karbon aktif Dari kulit pisang kepok (musa paradisiaca l.) Sebagai adsorben Senyawa polisiklik aromatik hidrokarbon fenantrena. Analit: Analytical and Environmental Chemistry, 3(02), 126–138.

Badan Standarisasi Nasional. (1995). SNI 06-3730-1995: Arang Aktif Teknis. In Badan Standarisasi Nasional.

Bhaumik, M., Choi, H. J., Seopela, M. P., Mccrindle, R. I., & Maity, A. (2014). Highly Effective Removal of Toxic Cr(VI) from Wastewater Using Sulfuric Acid-Modified Avocado Seed. In Industrial & Engineering Chemistry Research (Vol. 53, Issue 3).

Budiono, A., Suhartana, & Gunawan. (2008). Pengaruh Aktivasi Arang Tempurung Kelapa dengan Asam Sulfat dan Asam Fosfat untuk Adsorpsi Fenol. E-Universitas Diponegoro, 4(1), 1–12.

Dewi, M. S., Budi, E., & Susilaningsih, E. (2015). Pemanfaatan Arang Aktif Kulit Pisang Raja Untuk Menurunkan Kadar Ion Pb (II). Indonesian Journal of Chemical Science, 4(3).

Dorothy, A., & Mideen, A. S. (2015). Adsorption of Methylene blue dye on activated carbon from rice husk. Available Online Www.Jocpr.Com Journal of Chemical and Pharmaceutical Research, 7(2), 761–765.

Erabee, I. K., Ahsan, A., Nik Daud, N. N., Idrus, S., Shams, S., Md Din, M. F., & Rezania, S. (2017). Manufacture of low-cost activated carbon using sago palm bark and date pits by physiochemical activation. BioResources, 12(1), 1916–1923.

Ethaib, S., Omar, R., Mustapa Kamal, S. M., Awang Biak, D. R., Syam, S., & Harun, M. Y. (2017). Microwave-Assisted Pretreatment of Sago Palm Bark. Journal of Wood Chemistry and Technology, 37(1), 26–42.

Fahma, R., & Loekitowati, P. (2003). Pengaruh konsentrasi H2SO4 dan temperatur karbonisasi terhadap kualitas karbon aktif dari ampas kopi. In Jurnal Penelitian Sains (Issue 13, pp. 13–20).

Flach, M. (1997). Sago palm : Metroxylon sagu Rottb. Diversity, 76.

Haryanto, B., Mubekti, & Putranto, A. T. (2015). Potensi dan Pemanfaatan Pati Sagu dalam Mendukung Ketahanan Pangan di Kabupaten Sorong Selatan Papua Barat. Pangan, 24(2).

Jawad, A. H., Rashid, R. A., Ishak, M. A. M., & Wilson, L. D. (2016). Adsorption of methylene blue onto activated carbon developed from biomass waste by H 2 SO 4 activation: kinetic, equilibrium and thermodynamic studies. Desalination and Water Treatment, 57(52), 25194–25206.

Kartika, G. F., Itnawita, I., Hanifah, T. A., Anita, S., Dewi, N. O. M., & Absus, S. (2017). Pengaruh Aktivator Terhadap Kemampuan Bubuk Biji Alpukat (Persea americana Mill) dalam Menjerap Ion Timbal (II). Chimica et Natura Acta, 5(1).

McClatchey, W., Manner, H. I., & Elevitch, C. R. (2006). Metroxylon amicarum, M. paulcoxii, M. sagu, M. salomonense, M. vitiense, and M. warburgii (sago palm). Traditional Trees of Pacific Islands: Their Culture, Environment, and Use. Permanent Agricultural Resources, Holualoa, Hawai ‘I, 2(April), 491–512.

Pari, G. (2011). Pengaruh Selulosa Terhadap Struktur Karbon Arang Bagian I: Pengaruh Suhu Karbonisasi. Jurnal Penelitian Hasil Hutan, 29(1), 33–45.

Rambli, J., Wan Abd Karim Ghani, W. A., & Mohd Salleh, M. A. (2018). Characterization of Sago-based Biochar as Potential Feedstock for Solid Fuel. Journal of Energy and Safety Technology (JEST), 1(2), 11–17.

Sahara, E., Dahliani, N. K., & Manuaba, I. B. P. (2017). Pembuatan Dan Karakterisasi Arang Aktif Dari Batang Tanaman Gumitir (Tagetes Erecta) Dengan Aktivator NaOH. Jurnal Kimia, 174.

Sastrohamidjojo, H. (1991). Spektroskopi. Liberty.Yogyakarta.

Siaka, I. M., Dona, P., Putri, O., & Suarsa, I. W. (2017). Pemanfaatan Arang Aktif dari Batang Tanaman Gumintir ( Tagetes erecta ) sebagai Adsorben Logam Berat Pb ( II ) dan Cd ( II ) dengan Aktivator NaOH. E-Journal Of Applied Chemistry, 5(2), 120–130.

Sukaya, Muliawati, endang setia, & Winardi, A. (2018). Peran keanekaragaman hayati untuk mendukung inodenesia sebagai lumbung pangan dunia. Seminar Nasional Dalam Rangka Dies Natalis UNS Ke 42 Tahun 2018, 2(1).

Suprabawati, A., Holiyah, N. W., & Jasmansyah, J. (2018). Kulit Singkong (Manihot esculenta Crantz) sebagai Karbon Aktif Dengan berbagai langkah pembuatan untuk Adsorpsi Logam Timbal (Pb2+) dalam air. Jurnal Kartika Kimia, 1(1).

Wahi, R., Chuah Abdullah, L., Nourouzi Mobarekeh, M., Ngaini, Z., & Choong Shean Yaw, T. (2017). Utilization of esterified sago bark fibre waste for removal of oil from palm oil mill effluent. Journal of Environmental Chemical Engineering, 5(1), 170–177.

Published
2021-05-01
How to Cite
., M., ., I., Chandra Kartika, A., & Filia Cani, F. (2021). Evaluasi Kemampuan HCl dan H2SO4 Sebagai Aktivator Adsorben Bubuk Kulit Batang Sagu (Metroxylon Sagu). Photon: Jurnal Sain Dan Kesehatan, 11(2), 111-120. https://doi.org/10.37859/jp.v11i2.2521
Section
Chemistry Sciences
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